Coal tar is a hazardous and toxic waste, a byproduct of coal gasification processes. Coal tar is a waste produced in industrial fields such as steel, power plant, and the cement industry. As a ...
In a process for obtaining substantially sulfur free pure naphthalene from bituminous coal tar and thionaphthene as a byproduct, a dephenolized thionaphthenecontaining naphthalene fraction from oxidative purification is extracted with concentrated sulfuric acid and acetic acid anhydride in benzene.
Coal tar, a black, sticky liquid thicker than water, is produced when coal is heated in the absence of air, a process called destructive distillation. Much coal tar is produced by the steel industry as it produces millions of tons of coke each year to fuel the furnaces used in separating iron from its ores.
It is a thin, colourless, highly flammable liquid with a characteristic smell. It is a good motor fuel solvent as well as being a feedstock for other benzene derivatives used in dye, insecticides and plastics production. At a later stage in the distillation process, a heavy coal tar solvent naphtha and a naphthalene fraction are produced.
Naphthalene is the most simple, commonly found, and most watersoluble PAHs in the environment. It is produced from coal tar fraction by crystallization and distillation. It is often used as dispersants in natural and synthetic rubbers, in the production of naphthalene sulfonate superplasticizers for concrete, in paints, tanning agents in the leather industry, in the production of the ...
This research presents the first demonstration of substantial microbial degradation and depletion of naphthalene from coal tar, a multicomponent, aromatic, dense nonaqueous phase liquid (NAPL). The rates and extents of microbial degradation of naphthalene from coal tar and from a twocomponent NAPL simpler in composition than coal tar were evaluated in gently mixed, NAPL−water batch systems ...
100 samples of recycle solvent were obtained by continuous operation (50 days) of 1 ton/day coal liquefaction plant at Kimitu. Naphthalene derivatives in the recycle solvents were anslyzed in ...
Naphthalene production and uses 299 Naphthalene recovery Coal tar is the traditional feedstock for the recovery of naphthalene. The introduc tion of new cracking processes in the last decades has given rise to the availability of petroleumbased raw materials. In addition to coalderived naphthalene, petro
Most naphthalene is derived from coal tar. From the 1960s until the 1990s, significant amounts of naphthalene were also produced from heavy petroleum fractions during petroleum refining, but presentday production is mainly from coal tar. Approximately tons are produced annually. Naphthalene is the most abundant single component of coal tar.
Naphthalene is the simplest polycyclic aromatic hydrocarbon, and can be used as a precursor to many other complex aromatics. Current industrial processes remove it from coal tar or petroleum during the refining and distillation steps. The process reported here is much greener, albeit on a much smaller scale.
Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
Naphthalene has a distinctive, strong odor, which is often described as sweet or tarlike. Its melting point is around 80°C (176°F), and it boils at around 218°C (424°F). Synthesis and Production. Naphthalene is predominantly produced from coal tar, a byproduct of the coal gasification process.
sumer products. Coal tars are used primarily for the production of refined chemicals and coaltar products, such as creosote, coaltar pitch, and crude naphthalene and anthracene oils from the distillation of crude coal tar. Coal tar has been used as a fuel in openhearth furnaces and blast furnaces in the steel industry, as a binder and filler in
Coal tar is an important raw material for the production of valuable aromatic compounds [].It has more than 500 components, most of which are aromatic hydrocarbons, including benzene, toluene, xylene, anthracene, naphthalene, and phenanthrene [4, 5].These are precursors for the synthesis of products such as dyes, drugs, explosives, scents, preservatives, synthetic tars, paints, and pigments.
The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic threecolumn system is Gcal/t of commercial naphthalene (of purity wt %). If heat is recycled in the threecolumn system, the energy consumption is ...
(a) The slow process of conversion of dead vegetation into coal is called carbonisation. (b) Coal and petroleum are formed from the dead remains of organisms and are known as fossil fuels. (c) The black thick liquid with unpleasant smell is known as coal tar. (d) During the processing of coal to get coke, coal tar and coal gas are also obtained. (e) The process of separating the various ...
The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic three ...
In the oxidation process, coal tar naphthalene and/or oxylene is vaporized, mixed with air and fed to the reactors. ... SUMMARY OF NAPHTHALENE EMISSIONS FROM ALL SOURCES Emission Source Coke byproduct recovery Naphthalene production Coal tar Petroleum Naphthalene end uses Inadvertent sources* Total All Sources Source Process 6. ...
Naphthalene, acenaphthene and luorene are wellknown organic chemicals that are useful as intermediates in the production of organic acids, dyes and insecticides. Previously acenaphthene and iluorene have been recovered from coal tar distillates or prepared by synthetic methods.
Coal tar. María Antonia Diez, Roberto Garcia, in New Trends in Coal Conversion, 2019. Concluding remarks. With coal tar as a byproduct from cokemaking, coal tar availability will continue to depend on the consumption of coke in the blast furnace for iron and steel production. Thus, the conditions of coke production in recovery coke ovens will play a decisive role in determining ...
Report No. COAL TAR CHEMICALS JAMES J. L. MA December 1976 A private report by the a PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA
An online condensation system was designed to separate coal tar during cooling process. ... The typical contents of most common specialties in different fractions for coal tar are Light oil, Phenol oil, Naphthalene oil, washing oil, anthracene oil. ... The production yield of total tar was about %, %, % and % for 500, 600, 700 ...
This report proffers the detailed cost evaluation of the production of naphthalene from coal tar. In this process, the coal tar is subjected to the distillation and fractionation process. Further, the middle fractions, which contain most of the naphthalene, are cooled and crystalized to yield crude naphthalene. Lastly, the crude naphthalene is ...
The coal tar evaluation process of its constituent components is carried out by distillation, with a high level of naphthalene purity achieved up to 96%. The coal tar distillation process normally ...
Naphthalene is an important component of high temperature coal tar and its content can reach more than 10%. Catalytic polycondensation of naphthalene is an effective way to prepare mesophase pitch and functional carbon materials. ... which may provide valuable hints for exploring the production process of mesophase naphthalene pitch. Declare of ...
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